REACTION OF SUPPORTED FLUORIDE-ION WITH GASEOUS SULFUR MUSTARD

Authors
BELLAMY AJ
Citation
Aj. Bellamy, REACTION OF SUPPORTED FLUORIDE-ION WITH GASEOUS SULFUR MUSTARD, Reactive polymers, 23(2-3), 1994, pp. 101-106
Citations number
6
Categorie Soggetti
Polymer Sciences","Engineering, Chemical","Chemistry Applied
Journal title
Reactive polymers → ACNP
ISSN journal
09231137
Volume
23
Issue
2-3
Year of publication
1994
Pages
101 - 106
Database
ISI
SICI code
0923-1137(1994)23:2-3<101:ROSFWG>2.0.ZU;2-Q
Abstract
The behaviour of supported fluoride ion when treated with gaseous sulp hur mustard, (ClCH2CH2)(2)S, has been studied. Amberlyst A-26 F- was f ound to have a large capacity for reaction (1.5 mmol S-mustard/g resin ), the only observed organic product being divinyl sulphide. Fluoride ion on other support materials showed much lower reaction capacity.