STUDIES ON THE MICROSTRUCTURE OF POLY(PHENYL GLYCIDYL ETHER) USING THE C-13 NUCLEAR-MAGNETIC-RESONANCE TECHNIQUE

Authors
RONDA JC SERRA A MANTECON A CADIZ V
Citation
Jc. Ronda et al., STUDIES ON THE MICROSTRUCTURE OF POLY(PHENYL GLYCIDYL ETHER) USING THE C-13 NUCLEAR-MAGNETIC-RESONANCE TECHNIQUE, Polymer, 36(3), 1995, pp. 471-478
Citations number
35
Categorie Soggetti
Polymer Sciences
Journal title
Polymer → ACNP
ISSN journal
00323861
Volume
36
Issue
3
Year of publication
1995
Pages
471 - 478
Database
ISI
SICI code
0032-3861(1995)36:3<471:SOTMOP>2.0.ZU;2-0
Abstract
Microstructural details of poly(phenyl glycidyl ether) (PPGE) and its optically active form obtained by the aluminium isopropoxide (AIP)/ZnC l2 ionic-coordinative initiator were analysed by nuclear magnetic reso nance techniques. In order to assign the soluble fraction signals unmi stakably, PPGE samples had to be synthesized using various cationic in itiator systems. Several modifications were studied in the AIP/ZnCl2 i nitiator system (such as the use of various zinc salts and the additio n of water) and the tacticity and irregularity contents of the polymer s were determined.