A. Datta et Dg. Baird, COMPATIBILIZATION OF THERMOPLASTIC COMPOSITES BASED ON BLENDS OF POLYPROPYLENE WITH 2 LIQUID-CRYSTALLINE POLYMERS, Polymer, 36(3), 1995, pp. 505-514
In an earlier paper we considered the effect of polypropylene modified
with maleic anhydride (MAGPP) on the properties of in situ composites
based on polypropylene (PP) and a thermotropic copolyesteramide (Vect
ra B). In this paper we consider the effect of MAGPP on the properties
of in situ composites based on PP and two different thermotropic copo
lyesters. It was observed that the MAGPP was nearly as effective in im
proving the properties for the copolyester systems as it was for the c
opolyesteramide system. The addition of MAGPP leads to finer and bette
r dispersed fibrils of liquid crystalline polymer relative to the blen
ds with no MAGPP added. These results were somewhat unexpected based o
n earlier reports which suggested that compatibility would be detrimen
tal to the formation of fibrils.