HYDRORUTHENATION OF PROP-2-YNYLTRIPHENYLPHOSPHONIUM BROMIDE - SYNTHESIS, CRYSTAL-STRUCTURE AND REACTIONS OF [RUBR(CH=CHCH(2)PPH(3))(CO)(PPH(3))(2)]PF6

Authors
ALCOCK NW CARTWRIGHT J HILL AF MARCELLIN M RAWLES HM
Citation
Nw. Alcock et al., HYDRORUTHENATION OF PROP-2-YNYLTRIPHENYLPHOSPHONIUM BROMIDE - SYNTHESIS, CRYSTAL-STRUCTURE AND REACTIONS OF [RUBR(CH=CHCH(2)PPH(3))(CO)(PPH(3))(2)]PF6, Journal of the Chemical Society, Chemical Communications, (3), 1995, pp. 369-370
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
3
Year of publication
1995
Pages
369 - 370
Database
ISI
SICI code
0022-4936(1995):3<369:HOPB-S>2.0.ZU;2-2
Abstract
The reaction of the complex [RuClH(CO)(PPh(3))(3)] with prop-2-ynyltri phenylphosphonium bromide ([Ph(3)PCH(2)C equivalent to CH]Br) followed by NH4PF6 provides the crystallographically characterised salt [RuBr( CH=CHCH(2)PPh(3))(CO)(PPh(3))(2)]PF6 which by virtue of the coordinati ve unsaturation at the ruthenium centre undergoes addition of the liga nds CNC(6)H(3)Me(2)-2,6, and CO to Ru and insertion of SO2 into the Ru -C sigma-bond.