INFRARED ANALYTICAL EVIDENCE OF OXYGEN-INDUCED FORMATION OF FE(CO)(5)FROM CO AND STEEL WALLS OF AN IN-SITU DRIFT CELL

Authors
DOSSI C RECCHIA S FUSI A
Citation
C. Dossi et al., INFRARED ANALYTICAL EVIDENCE OF OXYGEN-INDUCED FORMATION OF FE(CO)(5)FROM CO AND STEEL WALLS OF AN IN-SITU DRIFT CELL, Annali di chimica, 84(7-8), 1994, pp. 347-352
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Annali di chimica → ACNP
ISSN journal
00034592
Volume
84
Issue
7-8
Year of publication
1994
Pages
347 - 352
Database
ISI
SICI code
0003-4592(1994)84:7-8<347:IAEOOF>2.0.ZU;2-T
Abstract
The formation of volatile Fe(CO)5 carbonyl from CO and the steel walls of an in situ IR cell has been investigated as the cause of iron cont amination of the samples. Correlation with the use of oxidizing atmosp heres, leading to a thin film of iron oxides on the cell walls, is als o discussed.