NOVEL BIODEGRADABLE COPOLYAMIDES BASED ON ADIPIC ACID, ISOPHORONE DIAMINE AND ALPHA-AMINO-ACIDS .3. SYNHESIS, STUDY OF PROPERTIES AND EVALUATION OF THEIR BIODEGRADABILITY FOR FOOD-PACKAGING APPLICATIONS
I. Arvanitoyannis et al., NOVEL BIODEGRADABLE COPOLYAMIDES BASED ON ADIPIC ACID, ISOPHORONE DIAMINE AND ALPHA-AMINO-ACIDS .3. SYNHESIS, STUDY OF PROPERTIES AND EVALUATION OF THEIR BIODEGRADABILITY FOR FOOD-PACKAGING APPLICATIONS, Die Angewandte makromolekulare Chemie, 221, 1994, pp. 67-90
Novel biodegradable copolyamides were synthesized by melt polycondensa
tion. Statistical copolymers were produced by the incorporation of alp
ha-amino acids showing a gradual increase in their T(g) but a decrease
in their tensile strength followed by higher susceptibility to alkali
hydrolysis which was confirmed with GPC measurements. The amorphous n
ature of these novel copolyamides was confirmed with the aid of wide-a
ngle X-ray diffraction patterns and differential thermal analysis. FT-
IR spectra of the copolymers confirmed the existence of the amino acid
moiety. These novel biodegradable copolyamides are expected to find a
pplication either on their own in the fields of food packaging and agr
iculture (disposable plastics) or as a part of composites, as sutures
for fixation of macroscopic implants.