Jj. Venkrbec et J. Kousal, MATERIALS ENGINEERING FOR OPTOELECTRONIC CRYSTALS RELATED TO III-V COMPOUNDS, Journal of thermal analysis, 43(2), 1995, pp. 377-388
An introductory glimpse of modern approaches to the application of pro
ductive and reasonable techniques for the defined electronic materials
will be presented. The paper is divided into four parts. Each is supp
lemented with illustrations. The first part explains the meaning of ma
terials engineering for electronics (MEE) and for optoelectronic cryst
als in particular. its interdisciplinarity is shown and also the range
of problems it can solve. Graduate courses of some MEE disciplines ar
e also given. The second part of the paper related to the feasible sol
ution with MEE as to the optimal realization of the application requir
ements. The physical modelling, databases and characterization techniq
ues are given. The third part deals with particular materials: III-V s
emiconductors. A brief survey of the best methods of crystal growth is
given, stressing those which imply a possibility of creating crystals
defined up to the atomic range. The last part is devoted to our team'
s original crystal growth methods: CAM-S (A Crystallization Method Pro
viding Composition Autocontrol in Situ) and COM-S (Calculation Method
of Optimal Molten-Solution Composition). The combination of these meth
ods, further modified with vibrational and magneto-hydrodinamical stir
ring (VS, MHD-S), allows us to grow crystalline ingots of ternary soli
d solutions (TSS) possessing extreme homogeneity. Illustrations on In-
Ga-Sb system are supplied. We conclude with a discussion of the impact
of such methods and approaches on a device quality and to other field
s.