TRANS-3-SILYL ALLYLIC ALCOHOLS VIA THE BROWN VINYLATION

Authors
RANE AM VAQUER J COLBERG JC SODERQUIST JA
Citation
Am. Rane et al., TRANS-3-SILYL ALLYLIC ALCOHOLS VIA THE BROWN VINYLATION, Tetrahedron letters, 36(7), 1995, pp. 987-990
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
7
Year of publication
1995
Pages
987 - 990
Database
ISI
SICI code
0040-4039(1995)36:7<987:TAAVTB>2.0.ZU;2-Q
Abstract
The addition of representative aldehydes to trans-vinylborane 1 provid ed pure trans-3-silyl allylic alcohols 2 in excellent yields. The comb ination of dehydroborylation and insertion leads to the novel dihydroi sobenzofuran 7.