ANTI-SELECTIVE ALKYLATION OF CARBOXYLATE ENOLATES WITH 2-SULFONYLOXYALKANES - A NEW ROUTE TO OPTICALLY-ACTIVE 2-ARYLALKANOIC ACIDS

Authors
KUSUMOTO T ICHIKAWA S ASAKA K SATO K HIYAMA T
Citation
T. Kusumoto et al., ANTI-SELECTIVE ALKYLATION OF CARBOXYLATE ENOLATES WITH 2-SULFONYLOXYALKANES - A NEW ROUTE TO OPTICALLY-ACTIVE 2-ARYLALKANOIC ACIDS, Tetrahedron letters, 36(7), 1995, pp. 1071-1074
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
7
Year of publication
1995
Pages
1071 - 1074
Database
ISI
SICI code
0040-4039(1995)36:7<1071:AAOCEW>2.0.ZU;2-T
Abstract
Reaction of arylacetic acid enolates with 2-tosyloxyalkanes gave with high anti-selectivity 2-aryl-3-methylalkanoic acids which were useful synthetic intermediates of ferroelectric liquid crystals.