The Electroreflectance spectra of a GaAs/Al0.3Ga0.7As asymmetric doubl
e quantum well have been studied from 30 K to room temperature. The ex
perimental spectra consist of various excitonic transition features of
the quantum well system above the GaAs band edge, and an inter-band t
ransition at the Al0.3Ga0.7As band gap. The first and the second elect
ronic subband in the wide well are partially filled by the ionized ele
ctrons from Si delta-doping centers in the Al0.3Ga0.7As barriers. The
corresponding optical transitions are weak and broadened in the optica
l spectra. The strongest spectra feature is due to a resonance between
the narrow well and wide well subbands. The modulated reflectance sig
nal, Delta R/R, is enhanced thermally by the wide well and narrow well
subband resonance. The observed optical transition energies agree wit
h the calculated subband energies obtained from the envelope wave func
tion model.