METAL-COMPLEXES IN INORGANIC MATRICES .13. NICKEL-COMPLEXES WITH LYSINATE-SUBSTITUTED TITANIUM ALKOXIDES AS LIGANDS - X-RAY STRUCTURE-ANALYSIS OF [(ETO)(3)TI(GLYCINATE)](2)

Authors
SCHUBERT U TEWINKEL S MOLLER F
Citation
U. Schubert et al., METAL-COMPLEXES IN INORGANIC MATRICES .13. NICKEL-COMPLEXES WITH LYSINATE-SUBSTITUTED TITANIUM ALKOXIDES AS LIGANDS - X-RAY STRUCTURE-ANALYSIS OF [(ETO)(3)TI(GLYCINATE)](2), Inorganic chemistry, 34(4), 1995, pp. 995-997
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
4
Year of publication
1995
Pages
995 - 997
Database
ISI
SICI code
0020-1669(1995)34:4<995:MIIM.N>2.0.ZU;2-M
Abstract
Reaction of Ti(OEt)(4) with amino acids results in alkoxide carboxylat e derivatives, in which the amino carboxylate group chelates the Ti(OE t)(3) moiety via one oxygen atom and the NH2 group. An X-ray structure analysis of the glycine derivative showed the compound to be dimeric, with the two Ti atoms bridged by two OEt group. When lysine is used, only the alpha-amino group coordinates to the metal while the terminal amino group is dangling and can be used to coordinate metal ions.