A. Nordmann et Yb. Cheng, CRYSTALLIZATION BEHAVIOR AND MICROSTRUCTURAL EVOLUTION OF A LI2O-AL2O3-SIO2 GLASS DERIVED FROM SPODUMENE MINERAL, Journal of Materials Science, 32(1), 1997, pp. 83-89
A naturally occurring mineral deposit of alpha-spodumene has been succ
essfully used to fabricate glasses and glass ceramics in the Li2O-Al2O
3-SiO2 (LAS) system. TiO2 is an effective nucleating agent in promotin
g the crystallization of Li2O-Al2O3-4SiO(2) glass to produce LAS glass
-ceramics in which beta-quartz(ss) and beta-spodumene(ss) are the majo
r crystalline phases evolved. The crystallization process and microstr
uctural evolution were monitored using X-ray diffraction and transmiss
ion electron microscopy.