CHARACTERIZATION OF ARTIFICIALLY PATINATED LAYERS ON ARTISTIC BRONZE EXPOSED TO LABORATORY SO2 CONTAMINATION

Citation
Jm. Bastidas et al., CHARACTERIZATION OF ARTIFICIALLY PATINATED LAYERS ON ARTISTIC BRONZE EXPOSED TO LABORATORY SO2 CONTAMINATION, Journal of Materials Science, 32(1), 1997, pp. 129-133
Citations number
21
Categorie Soggetti
Material Science
ISSN journal
00222461
Volume
32
Issue
1
Year of publication
1997
Pages
129 - 133
Database
ISI
SICI code
0022-2461(1997)32:1<129:COAPLO>2.0.ZU;2-D
Abstract
Artificially patinated artistic bronze was exposed to the action of 0. 10 and 12.68 ppm SO2 contamination in the laboratory at 100% relative humidity. The surface layers were characterized using electrochemical, atomic absorption, X-ray powder diffraction techniques and Fourier tr ansform-infrared spectrometry. Thermal and calorimetric studies were a lso performed. Some of the compounds identified were cuprite (Cu2O), d igenite (Cu1.8S), yarrowite (Cu9S8), chalcocite (Cu2S), brochantite (C u-4(OH)(6)SO4), bonattite (CuSO4 . 3H(2)O) and Sn2S3.