Jm. Bastidas et al., CHARACTERIZATION OF ARTIFICIALLY PATINATED LAYERS ON ARTISTIC BRONZE EXPOSED TO LABORATORY SO2 CONTAMINATION, Journal of Materials Science, 32(1), 1997, pp. 129-133
Artificially patinated artistic bronze was exposed to the action of 0.
10 and 12.68 ppm SO2 contamination in the laboratory at 100% relative
humidity. The surface layers were characterized using electrochemical,
atomic absorption, X-ray powder diffraction techniques and Fourier tr
ansform-infrared spectrometry. Thermal and calorimetric studies were a
lso performed. Some of the compounds identified were cuprite (Cu2O), d
igenite (Cu1.8S), yarrowite (Cu9S8), chalcocite (Cu2S), brochantite (C
u-4(OH)(6)SO4), bonattite (CuSO4 . 3H(2)O) and Sn2S3.