COMPLETE PI-FACIAL STEREOSELECTIVITY IN THE TICL4-MEDIATED [4-FUMAROYLDI[(2R)-BORNANE-10,2-SULTAM](2] CYCLOADDITION OF CYCLOPENTADIENE TO N,N')

Authors
CHAPUIS C RZEPECKI P BAUER T JURCZAK J
Citation
C. Chapuis et al., COMPLETE PI-FACIAL STEREOSELECTIVITY IN THE TICL4-MEDIATED [4-FUMAROYLDI[(2R)-BORNANE-10,2-SULTAM](2] CYCLOADDITION OF CYCLOPENTADIENE TO N,N'), Helvetica Chimica Acta, 78(1), 1995, pp. 145-150
Citations number
111
Categorie Soggetti
Chemistry
Journal title
Helvetica Chimica Acta → ACNP
ISSN journal
0018019X
Volume
78
Issue
1
Year of publication
1995
Pages
145 - 150
Database
ISI
SICI code
0018-019X(1995)78:1<145:CPSITT>2.0.ZU;2-1
Abstract
Under the co-operative influence of two prosthetic groups, and indepen dent of the TiCl4 concentration, complete and constant diastereofacial pi-selection was achieved during the [4 + 2] cycloaddition of cyclope ntadiene to N,N'-fumaroyl-di[(2R)-bornane-10,2-sultam] ((-)-1c); react ive conformations are discussed.