CORRELATIONS BETWEEN F-19 NMR CHEMICAL-SHIFTS AND BOND-DISSOCIATION ENERGIES, ENTHALPIES OF FORMATION AND GROUP ELECTRONEGATIVITIES

Authors
COBOS CJ CAPPARELLI AL
Citation
Cj. Cobos et Al. Capparelli, CORRELATIONS BETWEEN F-19 NMR CHEMICAL-SHIFTS AND BOND-DISSOCIATION ENERGIES, ENTHALPIES OF FORMATION AND GROUP ELECTRONEGATIVITIES, Journal of fluorine chemistry, 70(2), 1995, pp. 155-162
Citations number
57
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
70
Issue
2
Year of publication
1995
Pages
155 - 162
Database
ISI
SICI code
0022-1139(1995)70:2<155:CBFNCA>2.0.ZU;2-R
Abstract
Correlations between F-19 NMR chemical shifts (phi) in fluorohalohydro carbons and enthalpies of formation, bond dissociation energies, group contribution to enthalpies of formation and enthalpies of formation o f free radicals are presented. A good correlation between these proper ties has been found with the square root of phi. A relationship betwee n fluorine chemical shifts and group electronegativities is also discu ssed.