NUCLEOPHILIC TRIFLUOROMETHYLATION OF ORGANIC SUBSTRATES USING (TRIFLUOROMETHYL)TRIMETHYLSILANE IN THE PRESENCE OF A FLUORIDE ANION - .2. A CONVENIENT ROUTE TO ARYLTRIFLUOROMETHYL-SULFIDES, ARYLTRIFLUOROMETHYL-SULFOXIDES AND ARYLTRIFLUOROMETHYL-SULFONES

Authors
MOVCHUN VN KOLOMEITSEV AA YAGUPOLSKII YL
Citation
Vn. Movchun et al., NUCLEOPHILIC TRIFLUOROMETHYLATION OF ORGANIC SUBSTRATES USING (TRIFLUOROMETHYL)TRIMETHYLSILANE IN THE PRESENCE OF A FLUORIDE ANION - .2. A CONVENIENT ROUTE TO ARYLTRIFLUOROMETHYL-SULFIDES, ARYLTRIFLUOROMETHYL-SULFOXIDES AND ARYLTRIFLUOROMETHYL-SULFONES, Journal of fluorine chemistry, 70(2), 1995, pp. 255-257
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
70
Issue
2
Year of publication
1995
Pages
255 - 257
Database
ISI
SICI code
0022-1139(1995)70:2<255:NTOOSU>2.0.ZU;2-L
Abstract
Aryltrifluoromethyl-sulfides, -sulfoxides and -sulfones can be prepare d by trifluoromethylation of the corresponding arylsulfenyl, -sulfinyl and -sulfonyl halides using (trifluoromethyl)trimethylsilane in the p resence of fluoride sources, such as TASF [tris(dimethylamino)sulfoniu m difluorotrimethylsilicate].