STEREOSELECTIVE INTRODUCTION OF THE DIFLU OROMETHYLENE GROUP IN THE ALLYL POSITION

Authors
TELLIER F SAUVETRE R
Citation
F. Tellier et R. Sauvetre, STEREOSELECTIVE INTRODUCTION OF THE DIFLU OROMETHYLENE GROUP IN THE ALLYL POSITION, Journal of fluorine chemistry, 70(2), 1995, pp. 265-270
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
70
Issue
2
Year of publication
1995
Pages
265 - 270
Database
ISI
SICI code
0022-1139(1995)70:2<265:SIOTDO>2.0.ZU;2-R
Abstract
The regio- and stereo-selective introduction of a difluoromethylene gr oup in an allylic position is described. The key step is the treatment of 1,1-difluoro-1-alken-3-acetates with Grignard reagents in the pres ence of copper and lithium salts.