THE ANHARMONIC EFFECT AS ORIGINATED FROM THE ASYMMETRY OF A ROTOR - THE CASE-STUDY OF AN ASYMMETRIC ROTOR COUPLED WITH A SIMPLE HARMONIC-OSCILLATOR

Authors
Citation
Gz. Wu, THE ANHARMONIC EFFECT AS ORIGINATED FROM THE ASYMMETRY OF A ROTOR - THE CASE-STUDY OF AN ASYMMETRIC ROTOR COUPLED WITH A SIMPLE HARMONIC-OSCILLATOR, Chemical physics, 214(1), 1997, pp. 15-21
Citations number
17
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
03010104
Volume
214
Issue
1
Year of publication
1997
Pages
15 - 21
Database
ISI
SICI code
0301-0104(1997)214:1<15:TAEAOF>2.0.ZU;2-6
Abstract
The dynamics of an asymmetric rotor coupled with a simple harmonic osc illator is studied in terms of the SU(2)/U(1) x H-4/U(1) x U(1) coset space representation. The expressions related to the anharmonic effect of an asymmetric rotor are elucidated and their impact on the dynamic s analyzed. The semiclassical regular and irregular (chaotic) trajecto ries of the coupled system are demonstrated with their relationship wi th the total rotational quantum number J and the asymmetry of the roto r stressed. It is concluded that not only J but also the degree of asy mmetry affect the accuracy of the harmonic treatment.