G. Lebras et U. Platt, A POSSIBLE MECHANISM FOR COMBINED CHLORINE AND BROMINE CATALYZED DESTRUCTION OF TROPOSPHERIC OZONE IN THE ARCTIC, Geophysical research letters, 22(5), 1995, pp. 599-602
Recent field measurements of BrO radical concentrations and estimates
of ClO radical concentrations from field measurements of hydrocarbons
have been used to calculate the ozone depletion rate in the Arctic bou
ndary layer which occurs during springtime. Considering the ozone cycl
es involving the ClO/BrO reaction and the BrO self-reaction the calcul
ated ozone depletion rates, as high as 6 ppb/day, are comparable to th
e observations.