SYNTHESIS OF ELECTRICALLY CONDUCTIVE POLY(P-PHENYLENEVINYLENE-CO-2,5-THIENYLENEVINYLE) [P(PV-CO-TV)]

Authors
Citation
Dy. Kim et al., SYNTHESIS OF ELECTRICALLY CONDUCTIVE POLY(P-PHENYLENEVINYLENE-CO-2,5-THIENYLENEVINYLE) [P(PV-CO-TV)], Synthetic metals, 69(1-3), 1995, pp. 497-498
Citations number
5
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Metallurigical Engineering
Journal title
ISSN journal
03796779
Volume
69
Issue
1-3
Year of publication
1995
Pages
497 - 498
Database
ISI
SICI code
0379-6779(1995)69:1-3<497:SOECP>2.0.ZU;2-7
Abstract
oly(p-phenylenevinylene-co-2,5-thienylenevinylene) [poly(PV-co-TV)] wa s prepared by the reaction of p-bis(methylenedimethylsulfoniumchloride ) phenylene(BMSP) and 2,5-bis(methylenedimethylsulfoniumchloride) thio phene(BMST) by the modified sulfonium polyelectrolyte precursor route. The synthesized precursor copolymer and final conjugated copolymer we re characterized by IR, UV, GPC and EA. The electrical conductivities of poly(PV-co-TV) ranged from 10(-11) to 10(-9) Scm(-1), depending on the composition of monomer in copolymer. The absorption maximum of pol y(PV-co-TV) appeared at 440nm.