RING-OPENING REACTIONS OF EPOXIDES CATALYZED BY SAMARIUM IODIDES

Citation
P. Vandeweghe et J. Collin, RING-OPENING REACTIONS OF EPOXIDES CATALYZED BY SAMARIUM IODIDES, Tetrahedron letters, 36(10), 1995, pp. 1649-1652
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
36
Issue
10
Year of publication
1995
Pages
1649 - 1652
Database
ISI
SICI code
0040-4039(1995)36:10<1649:RROECB>2.0.ZU;2-8
Abstract
SmI2(THF)(2) catalyzes the ring opening of epoxides by trimethylsilyla zide, trimethylsilylcyanide and primary and secondary amines. High reg ioselectivities are observed in specific cases.