Ws. Maclachlan et Sa. Readshaw, STEREOSELECTIVE SYNTHESIS OF 13-DEHYDROXY-(14S)-HYDROXYAMPHOTERICIN-BMETHYL-ESTER, Tetrahedron letters, 36(10), 1995, pp. 1735-1738
Stereoselective hydroboration of 6 affords, after further manipulation
, 13-dehydroxy-(14S)-hydroxyamphotericin B methyl ester 9, the first a
mphotericin B derivative with a saturated ether function at C-13.