CORRELATION BETWEEN THE HYBRIDIZATION STRENGTH AND THE CE TO CE-LIGAND SPACING IN CET(2)X(2) COMPOUNDS

Citation
Jg. Sereni et O. Trovarelli, CORRELATION BETWEEN THE HYBRIDIZATION STRENGTH AND THE CE TO CE-LIGAND SPACING IN CET(2)X(2) COMPOUNDS, Journal of magnetism and magnetic materials, 144, 1995, pp. 885-886
Citations number
9
Categorie Soggetti
Material Science","Physics, Condensed Matter
ISSN journal
03048853
Volume
144
Year of publication
1995
Part
2
Pages
885 - 886
Database
ISI
SICI code
0304-8853(1995)144:<885:CBTHSA>2.0.ZU;2-Y
Abstract
The hybridization strength of the Ce-4f electrons with d or p orbitals of neighbouring sites, is analyzed through the comparison of the Ce-T and Ce-X spacings in CeT(2)X(2) compounds. Four different regimes, di rectly related to the increase of the hybridization strength, are reco gnized. This systematic indicates that the Ce behaviour depends more s trongly on the overlap of f-p than of f-d orbitals.