Large enhancements of the magnetic cross section of photons occurs whe
n the energy is tuned near to an absorption edge. Examples of this eff
ect in the actinides at the M(IV) edge are presented. The excellent re
solution available with X-ray synchrotron beams has allowed new featur
es in both the magnetic structure and the critical regime to be determ
ined. The technique is also sensitive to the near-surface region. Some
of the possibilities with the new 3rd-generation synchrotrons will be
discussed.