In Tyrrhenian Central Italy large amounts of CO2 are produced at depth
mainly by metamorphism of marine carbonate rocks. During their ascent
, the gases are trapped in deep structures, made up of Mesozoic permea
ble limestones covered by impermeable terrains, which become sources o
f a high CO, flux toward the surface. The anomalous CO2 concentrations
are delectable in groundwaters. The general map of the groundwater PC
O2 values shows a decrease in the CO2 production moving from the weste
rn geothermal areas of Tuscany and Latium to the eastern sector, which
is characterized by a normal heat flow. The PCO2 distribution suggest
s that the NW-SE extensional faults, which bound Plio-Pleistocene grab
ens, provide the easiest routes for the gas ascent. The geological, ge
ophysical and geothermal deep drilling data suggest that the CO2 anoma
lies found in the western sector correspond to deep permeable structur
es of possible geothermal interest.