THE FIRST EXAMPLE OF ALPHA-ORGANOSELENO ARSONIUM YLIDES AND ITS WITTIG-TYPE REACTION

Citation
Zz. Huang et al., THE FIRST EXAMPLE OF ALPHA-ORGANOSELENO ARSONIUM YLIDES AND ITS WITTIG-TYPE REACTION, Journal of organometallic chemistry, 490(1-2), 1995, pp. 23-26
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
490
Issue
1-2
Year of publication
1995
Pages
23 - 26
Database
ISI
SICI code
0022-328X(1995)490:1-2<23:TFEOAA>2.0.ZU;2-S
Abstract
alpha-Organoseleno arsonium ylide 3 was synthesized for the first time by a phenylselenenylation-transylidation reaction. It has sufficient activity to carry out the Wittig-type reaction, affording a novel meth od for the stereoselective synthesis of (Z)-alpha-phenylseleno-alpha,b eta-unsaturated esters