Re. Boltnev et al., THE METASTABLE NE(P-3(2)) AND N(D-2) ATOMS IN CORES OF SOLITARY AND STICKING HELIUM CLUSTERS HELIUM SURROUNDING AND HEAVY NEIGHBOR INFLUENCE, Journal de chimie physique et de physico-chimie biologique, 92(2), 1995, pp. 362-383
The fluorescence excitation spectra oi metastable P-3(2) Ne atoms in s
uperfluid helium have been studied for the first time. Ne spectral lin
es show a surprisingly small broadening and shift. We have also studie
d emission spectra and decay times related to the strongly forbidden N
(D-2 --> S-4) transition in the impurity-helium solid phase (IHSP) con
taining metastable N atoms, N-2 molecules and - in some cases - rare g
as atoms (Rg = Ne or Kr). We have shown that the central cores of soli
d He clusters correspond to single metastable N(D-2) atoms or to N*-N
-2 and N-Rg pairs as well as to triple N*-N-2-Rg and exciton-like N*R
g(n), complexes, as evidenced by their luminescence spectra.