Pr. Teasdale et Gg. Wallace, IN-SITU CHARACTERIZATION OF CONDUCTING POLYMERS BY MEASURING DYNAMIC CONTACT ANGLES WITH WILHELMYS PLATE TECHNIQUE, Reactive polymers, 24(3), 1995, pp. 157-164
Dynamic contact angle analysis with Wilhelmy's plate technique was fou
nd to be useful for characterizing the chemical interactions that occu
r on conducting polymers. The derivatized pyrroles, 3-carboxy-4-methyl
pyrrole and 3-carbethoxy-4-methylpyrrole, along with pyrrole, were use
d to prepare polymers with a range of polarities. The predicted trend
of polarity, based upon the chemical structures of the polymers, was v
erified with the technique. It has also been shown that the substrate
employed during electropolymerization process plays a major role in de
termining the properties of the resultant polymer.