DEACTIVATION OF A COAL-LIQUEFACTION CATALYST

Citation
Tj. Zhang et al., DEACTIVATION OF A COAL-LIQUEFACTION CATALYST, Fuel, 74(3), 1995, pp. 431-436
Citations number
15
Categorie Soggetti
Energy & Fuels","Engineering, Chemical
Journal title
FuelACNP
ISSN journal
00162361
Volume
74
Issue
3
Year of publication
1995
Pages
431 - 436
Database
ISI
SICI code
0016-2361(1995)74:3<431:DOACC>2.0.ZU;2-N
Abstract
A commercial coal liquefaction catalyst, Amocat 1A, has been subjected to a deactivation study in a laboratory catalytic coal liquefaction m icroreactor. Carbonaceous and metal deposits were the two major factor s causing catalyst deactivation. The carbonaceous material deposited p rimarily in the interior of the catalyst particle and clogged the pore s in a uniform manner. The metals deposit was rich in calcite and depo sition was mostly restricted to the external surface of the catalyst p article. It appears that either mechanism operating alone will complet ely deactivate the catalyst after processing roughly 1000 weights of c oal per weight of catalyst.