A commercial coal liquefaction catalyst, Amocat 1A, has been subjected
to a deactivation study in a laboratory catalytic coal liquefaction m
icroreactor. Carbonaceous and metal deposits were the two major factor
s causing catalyst deactivation. The carbonaceous material deposited p
rimarily in the interior of the catalyst particle and clogged the pore
s in a uniform manner. The metals deposit was rich in calcite and depo
sition was mostly restricted to the external surface of the catalyst p
article. It appears that either mechanism operating alone will complet
ely deactivate the catalyst after processing roughly 1000 weights of c
oal per weight of catalyst.