Complementary neutron diffraction and anomalous X-ray diffraction tech
niques are used to probe the nature and origin of local and intermedia
te-range order in cesium germanate glass. Both neutron and differentia
l X-ray structure factors reveal peaks at low wave vector associated w
ith intermediate-range order. The real-space correlation functions sho
w that the local interatomic correlations in the glass are similar to
those in the reference crystal Rb2Ge4O9 and imply a homogeneous distri
bution of Cs+ cations.