S. Chibowski et M. Paszkiewicz, STUDIES OF THE EFFECT OF ACETATE GROUPS IN THE MOLECULE OF POLYVINYL-ALCOHOL ON ITS ADSORPTION ON TIO2, Polish Journal of Chemistry, 69(3), 1995, pp. 461-466
The influence of acetate groups in a macromolecule of polyvinyl alcoho
l (OVA) on its adsorption properties and on the zeta potential of tita
nia was studied. A significant effect of acetate groups on the magnitu
de of PVA adsorption on TiO2 was found. Adsorption of PVA with acetate
groups affects also the zeta potential and the position of isoelectri
c point of TiO2. The change in the zeta potential is chiefly due to th
e charge of adsorbing PVA molecules. Ultimately, PVA adsorption change
s the structure of the electric double layer.