STRUCTURE ELUCIDATION OF A GLYCOSIDE OF BETA,3-BETA-23-TRIHYDROXY-16-OXOOLEAN-12-EN-28-OIC ACID FROM BELLIS-BERNARDII USING MASS-SPECTROMETRY FOR THE SUGAR SEQUENCE DETERMINATION

Authors
SCHOPKE T THIELE H WRAY V NIMTZ M HILLER K
Citation
T. Schopke et al., STRUCTURE ELUCIDATION OF A GLYCOSIDE OF BETA,3-BETA-23-TRIHYDROXY-16-OXOOLEAN-12-EN-28-OIC ACID FROM BELLIS-BERNARDII USING MASS-SPECTROMETRY FOR THE SUGAR SEQUENCE DETERMINATION, Journal of natural products, 58(1), 1995, pp. 152-155
Citations number
11
Categorie Soggetti
Chemistry,"Plant Sciences","Pharmacology & Pharmacy
Journal title
Journal of natural products → ACNP
ISSN journal
01633864
Volume
58
Issue
1
Year of publication
1995
Pages
152 - 155
Database
ISI
SICI code
0163-3864(1995)58:1<152:SEOAGO>2.0.ZU;2-Z
Abstract
The structure of a novel saponin, possessing an unusual aglycone named bellisonic acid and isolated from whole plants of Bellis bernardii, h as been elucidated by modern ms and nmr techniques as 3-O-alpha-L-rham nopyranosyl-2 beta,3 beta,23-trihydroxy-16-oxoolean-12-en-28-oic acid pha-L-rhamnopyranosyl(1-->2)-beta-D-fucopyranoside [1]. Ms procedures of general applicability allowed unambiguous sugar sequence determinat ion from very small amounts of material.