Melamine has shown broad utility as a flame retardant in plastics alth
ough its commercial use to date as a flame retardant additive has been
principally in coatings and flexible methane foams. Its mode of actio
n appears to involve endothermic sublimation and vapor-phase dissociat
ion, but it also undergoes conversion to non-volatile products and amm
onia. Combinations of melamine with other flame retardants of all type
s have been reported as having advantageous performance. The present r
eview covers the patent and non-patent literature with 130 references.