A FACILE SYNTHESIS OF DISILOXANES WITH FUNCTIONAL-GROUPS

Citation
A. Mori et al., A FACILE SYNTHESIS OF DISILOXANES WITH FUNCTIONAL-GROUPS, Chemistry Letters, (2), 1995, pp. 107-108
Citations number
12
Categorie Soggetti
Chemistry
Journal title
ISSN journal
03667022
Issue
2
Year of publication
1995
Pages
107 - 108
Database
ISI
SICI code
0366-7022(1995):2<107:AFSODW>2.0.ZU;2-A
Abstract
A facile synthetic method to obtain mono and difunctionalized disiloxa nes, which can be used as various monomers for speciality polymers is described. The ring-opening of cyclic siloxanes with functionalized or ganometallic reagents followed by quenching with a variety of silyl ch lorides gives the functionalized disiloxanes in good to excellent yiel ds.