LIGAND ENDOR STUDY OF THE TRIGONAL BIPYRAMIDAL COPPER-COMPLEXES, [CU(TREN)NH3](CLO4)(2) AND [CU(TREN)NCS]SCN IN THE POWDER STATE (TREN=TRIS(2-AMINOETHYL)AMINE)

Authors
EHSAN MQ OHBA Y YAMAUCHI S IWAIZUMI M
Citation
Mq. Ehsan et al., LIGAND ENDOR STUDY OF THE TRIGONAL BIPYRAMIDAL COPPER-COMPLEXES, [CU(TREN)NH3](CLO4)(2) AND [CU(TREN)NCS]SCN IN THE POWDER STATE (TREN=TRIS(2-AMINOETHYL)AMINE), Chemistry Letters, (2), 1995, pp. 151-152
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
2
Year of publication
1995
Pages
151 - 152
Database
ISI
SICI code
0366-7022(1995):2<151:LESOTT>2.0.ZU;2-N
Abstract
The HFC and NQC constants for all the coordinating atoms of the ligand tren, tris(2-aminoethyl)amine, in the trigonal bipyramidal (tbp) copp er complexes [Cu(tren)NH3](ClO4)(2) 1 and [Cu(tren)NCS]SCN 2 have been determined from the angle selected ENDOR study in the powder state. T he spin distribution and the metal ligand bonding nature in the copper (tbp) complexes are discussed.