BOTRYLACTONE SYNTHESIS AND STRUCTURE REVISION - A CONVERGENT APPROACHFROM D-GLUCOSE

Authors
BRUNS W HORNS S REDLICH H
Citation
W. Bruns et al., BOTRYLACTONE SYNTHESIS AND STRUCTURE REVISION - A CONVERGENT APPROACHFROM D-GLUCOSE, Synthesis, (3), 1995, pp. 335-342
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
3
Year of publication
1995
Pages
335 - 342
Database
ISI
SICI code
0039-7881(1995):3<335:BSASR->2.0.ZU;2-T
Abstract
A convergent approach for the synthesis of botrylactone I, an antibiot ic from the fungus Botrytis cinerea, from D-glucose is presented. The synthesis is carried out with an overall yield of 0.74% and a diastere oselectivity of > 95%. The originally published structure 2 must be re vised.