RESONANT AND NONRESONANT X-RAY-SCATTERING FROM C-70

Citation
Jh. Guo et al., RESONANT AND NONRESONANT X-RAY-SCATTERING FROM C-70, Chemical physics letters, 235(1-2), 1995, pp. 152-159
Citations number
22
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
235
Issue
1-2
Year of publication
1995
Pages
152 - 159
Database
ISI
SICI code
0009-2614(1995)235:1-2<152:RANXFC>2.0.ZU;2-D
Abstract
Resonant and non-resonant X-ray scattering spectra of the C-70 molecul e are presented and analyzed by ab initio Hartree-Fock calculations us ing a newly developed formalism for symmetry selective inelastic X-ray scattering. Compared to C-60, a weak excitation energy dependence of the spectral features is observed. The change from 'soccer-ball' (I-h) to 'rugby-bail' (D-5h) shapes leads to less symmetry selectivity but larger polarization selectivity. In contrast to C-60, the RIXS spectru m of C-70 molecule is dense even for narrow-band excitation.