THE CHEMISTRY OF 5-OXODIHYDROISOXAZOLES .13. REACTIONS OF THE IMINO CARBENE DERIVED FROM PHOTOLYSIS OF ETHYL 5-OXO-2-PHENYL-2,5-DIHYDROISOXAEOLE-4-CARBOXYLATE

Authors
ANG KH PRAGER RH WILLIAMS CM
Citation
Kh. Ang et al., THE CHEMISTRY OF 5-OXODIHYDROISOXAZOLES .13. REACTIONS OF THE IMINO CARBENE DERIVED FROM PHOTOLYSIS OF ETHYL 5-OXO-2-PHENYL-2,5-DIHYDROISOXAEOLE-4-CARBOXYLATE, Australian Journal of Chemistry, 48(3), 1995, pp. 567-575
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Australian Journal of Chemistry → ACNP
ISSN journal
00049425
Volume
48
Issue
3
Year of publication
1995
Pages
567 - 575
Database
ISI
SICI code
0004-9425(1995)48:3<567:TCO5.R>2.0.ZU;2-I
Abstract
Photolysis of ethyl 5-oxo-2-phenyl-2,5-dihydroisoxazole-4-carboxylate at 300 nm in acetonitrile gives a carbene which is captured efficientl y by bromide, chloride, acetate and cyanate, and less efficiently by i odide, thiocyanate, cyclohexene and tetrahydrofuran. No hydrogen abstr action or reaction with double bonds was evident.