SYNTHESIS AND X-RAY STRUCTURAL INVESTIGATION OF 6-CHLORO-10-PHENYL-1,2,3,4-TETRAHYDROACRIDINE

Authors
PONOMAREV II SHISHKIN OV LINDEMAN SV VOLKOVA YA
Citation
Ii. Ponomarev et al., SYNTHESIS AND X-RAY STRUCTURAL INVESTIGATION OF 6-CHLORO-10-PHENYL-1,2,3,4-TETRAHYDROACRIDINE, Russian chemical bulletin, 43(8), 1994, pp. 1390-1391
Citations number
3
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
8
Year of publication
1994
Pages
1390 - 1391
Database
ISI
SICI code
1066-5285(1994)43:8<1390:SAXSIO>2.0.ZU;2-V
Abstract
An X-ray structural study of 6-chloro-10-phenyl-1,2,3,4-tetrahydroacri dine prepared by the reaction of cyclohexanone with 2-amino-5-chlorobe nzofenone was carried out. At 20 degrees C a=24.215(6), b=8.967(2), c= 15.006(3) Angstrom, beta = 115.57(2)degrees, V=2939(1) Angstrom(3), d( calc) = 1.310 g cm(-3), Z=4, space group C2/c, 1324 reflections, lambd a MoK alpha, R=0.038. The cyclohexene ring has a half-chair conformati on. The phenyl substituent is rotated 71.2 degrees with respect to the plane of the quinoline fragment.