HETEROGENEOUS CATALYTIC TRANSFORMATION OF ISOBUTYL BENZOATE BY THE INVERSE TISHCHENKO REACTION

Authors
GLEBOV LS SHUIKIN AN KLIGER GA
Citation
Ls. Glebov et al., HETEROGENEOUS CATALYTIC TRANSFORMATION OF ISOBUTYL BENZOATE BY THE INVERSE TISHCHENKO REACTION, Russian chemical bulletin, 43(8), 1994, pp. 1417-1419
Citations number
4
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
8
Year of publication
1994
Pages
1417 - 1419
Database
ISI
SICI code
1066-5285(1994)43:8<1417:HCTOIB>2.0.ZU;2-X
Abstract
Using the catalytic transformation of isobutyl benzoate at 663 K in th e presence of 12 % MnO2/gamma-Al2O3 in a He atmosphere as an example, it has been shown that the inverse Tishchenko reaction can take place at a temperature above 600 K. Isobutyl benzoate gives isobutanal and b enzaldehyde as well as products of their transformation, i.e., benzyl isobutyrate, isobutanol, benzyl alcohol, and toluene.