MOLYBDENUM(IV) AZAMOLYBDATRANES CLMO(R(3)SINCH(2)CH(2))(3)N FROM AN UNEXPECTED REACTION

Authors
DUAN ZB VERKADE JG
Citation
Zb. Duan et Jg. Verkade, MOLYBDENUM(IV) AZAMOLYBDATRANES CLMO(R(3)SINCH(2)CH(2))(3)N FROM AN UNEXPECTED REACTION, Inorganic chemistry, 34(6), 1995, pp. 1576-1578
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
6
Year of publication
1995
Pages
1576 - 1578
Database
ISI
SICI code
0020-1669(1995)34:6<1576:MACFAU>2.0.ZU;2-H
Abstract
The azamolybdatranes ClMo(Me(3)SiNCH(2)CH(2))(3)N, 2a, and ClMo(t-BuMe (2)SiNCH(2)CH(2))(3)N, 2b, were prepared by the reaction of MoCl3(THF) (3) and the corresponding lithiated tetramines. The mu(eff) for 2a is 2.35 mu(B). This compound was structurally characterized in the solid state by X-ray diffraction. Crystal data: cubic, a = 17.199(1) Angstro m, V = 5087.6(11) Angstrom(3), Z = 8, space group Pa3 $$($) over bar, R = 2.7%.