CATIONIC TRINUCLEAR 48-ELECTRON RUTHENIUM CARBONYL CLUSTER COMPLEXES CONTAINING NO HYDRIDE LIGANDS

Authors
CABEZA JA DELRIO I LLAMAZARES A RIERA V GARCIAGRANDA S VANDERMAELEN JF
Citation
Ja. Cabeza et al., CATIONIC TRINUCLEAR 48-ELECTRON RUTHENIUM CARBONYL CLUSTER COMPLEXES CONTAINING NO HYDRIDE LIGANDS, Inorganic chemistry, 34(6), 1995, pp. 1620-1623
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
6
Year of publication
1995
Pages
1620 - 1623
Database
ISI
SICI code
0020-1669(1995)34:6<1620:CT4RCC>2.0.ZU;2-E
Abstract
The compound [Ru-3(mu(3)-ampy)(CO)(10)][BF4] (Hampy = 2-amino-6-methyl pyridine), the first cationic 48-electron trinuclear carbonyl cluster bearing no hydride ligands, has been prepared in a one-pot synthesis ( 93% isolated yield) from [Ru-3(mu-H)(mu(3)-ampy)(CO)9], diphenylacetyl ene, HBF4 . OEt(2), and CO. Some substitution chemistry of [Ru-3(mu(3) -ampy)(CO)(10)][BF4] and the X-ray structure of [Ru-3(mu(3)-ampy)(CO)( 9)(PPh(3))][BF4] C5H12 are also reported.