PROPERTIES OF SOME DERIVATIVES OF 3,3-DISUBSTITUTED PROPA-1,2-DIENESULFINIC ACIDS

Authors
BAUDIN JB JULIA SA RUEL O TOUPET L WANG Y
Citation
Jb. Baudin et al., PROPERTIES OF SOME DERIVATIVES OF 3,3-DISUBSTITUTED PROPA-1,2-DIENESULFINIC ACIDS, Bulletin de la Societe chimique de France, 132(1), 1995, pp. 79-85
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
132
Issue
1
Year of publication
1995
Pages
79 - 85
Database
ISI
SICI code
0037-8968(1995)132:1<79:POSDO3>2.0.ZU;2-H
Abstract
The title acids are formed by in situ acidic hydrolysis of the corresp onding N-morpholinosulfinamides 1. They undergo disproportionation to give thiosulfonates 2 and the unusual compounds 3. Anhydrous protonati on of two allenic t-butyl sulfinates 6 affords the alpha,beta-unsatura ted gamma-sultines 7.