SPECIFIC CATALYST ACTIVITY IN TERMS OF THE HETEROGENEOUS HOMOGENEOUS MECHANISM - INVERSION OF THE BORESKOV RULE

Authors
GOLODETS GI ILCHENKO NI
Citation
Gi. Golodets et Ni. Ilchenko, SPECIFIC CATALYST ACTIVITY IN TERMS OF THE HETEROGENEOUS HOMOGENEOUS MECHANISM - INVERSION OF THE BORESKOV RULE, Kinetics and catalysis, 36(1), 1995, pp. 27-30
Citations number
16
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
36
Issue
1
Year of publication
1995
Pages
27 - 30
Database
ISI
SICI code
0023-1584(1995)36:1<27:SCAITO>2.0.ZU;2-4
Abstract
For the heterogeneous-homogeneous catalytic reactions, the Boreskov ru le of the constancy of the specific catalytic activity r(sp) may be in verted: within the group of similar catalysts, r(sp) is determined mai nly by the surface area S. The specific catalytic activity decreases w ith increasing S according to the r(sp) = A/(1 + BS) dependence, where A and B are constants.