INVESTIGATION OF THE KINETIC RELATIONSHIPS GOVERNING THE HYDROFORMYLATION OF ISOBUTENE

Authors
KURKIN VI SAKULIN VV KOBYAKOV AK SLIVINSKII YV BASNER MY ARONOVICH RA KORNEYEVA GA LOKTEV SM
Citation
Vi. Kurkin et al., INVESTIGATION OF THE KINETIC RELATIONSHIPS GOVERNING THE HYDROFORMYLATION OF ISOBUTENE, Petroleum chemistry, 34(5), 1994, pp. 393-398
Citations number
9
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
34
Issue
5
Year of publication
1994
Pages
393 - 398
Database
ISI
SICI code
0965-5441(1994)34:5<393:IOTKRG>2.0.ZU;2-1
Abstract
A study has been made of the kinetic relationships governing the hydro formylation of isobutene in the presence of an etriolphosphite-modifie d carbonyl-rhodium catalyst. A mathematical model of the kinetics of h ydroformylation of isobutene has been obtained, satisfactorily describ ing the dependence of the rate of the reaction on the concentration of the reactants and the reaction conditions in a wide range of variatio n. The multiple correlation coefficient R amounts to 0.94. The activat ion energy of 3-methylbutanal formation E has been calculated at 78 +/ - 2 kJ/mole.