DIMERIZATION OF ETHYLENE IN ETHYL CHLORIDE IN THE PRESENCE OF THE CATALYTIC-SYSTEM TI(OC4H9)(4)-AL(C2H5)(3) UNDER THE CONDITIONS OF A CONTINUOUS PROCESS

Authors
GERASINA MP BRIKENSHTEIN AA BELOV GP
Citation
Mp. Gerasina et al., DIMERIZATION OF ETHYLENE IN ETHYL CHLORIDE IN THE PRESENCE OF THE CATALYTIC-SYSTEM TI(OC4H9)(4)-AL(C2H5)(3) UNDER THE CONDITIONS OF A CONTINUOUS PROCESS, Petroleum chemistry, 34(5), 1994, pp. 421-424
Citations number
1
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
34
Issue
5
Year of publication
1994
Pages
421 - 424
Database
ISI
SICI code
0965-5441(1994)34:5<421:DOEIEC>2.0.ZU;2-0
Abstract
A study has been made of the influence of temperature, ethylene pressu re, Ti(OC4H9)(4) concentration and contact time on the dimerization ra te of ethylene to but-1-ene under the operating conditions of a contin uous trial unit. It has been established that dimerization proceeds wi th a selectivity of 98-99% and a yield of up to 200 kg of but-1-ene pe r kg of Ti(OC4H9)(4).