DIELS-ALDER REACTIONS OF 2-BROMO-2-CYCLOALKENONES - A CONVENIENT APPROACH TO THE DOUBLY CISOID FULLY CONJUGATED DIENONE SYSTEM

Authors
LIU HJ SHIA KS
Citation
Hj. Liu et Ks. Shia, DIELS-ALDER REACTIONS OF 2-BROMO-2-CYCLOALKENONES - A CONVENIENT APPROACH TO THE DOUBLY CISOID FULLY CONJUGATED DIENONE SYSTEM, Tetrahedron letters, 36(11), 1995, pp. 1817-1820
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
11
Year of publication
1995
Pages
1817 - 1820
Database
ISI
SICI code
0040-4039(1995)36:11<1817:DRO2-A>2.0.ZU;2-6
Abstract
Under stannic chloride catalysis, 2-bromo-2-cycloalkenones 1 and 2 wer e found to undergo Diels-Alder reaction with dienes to give adducts in high yields. Subsequent treatment of the adducts with 1,8-diazabicycl o[5,4.0]undec-7-ene gave the corresponding doubly cisoid fully conjuga ted dienones.