REACTIONS OF EPISULFONIUM IONS FROM THE SULFENYLATION OF ALKENES AND FROM PHENYLTHIO MIGRATION - KINETIC VS THERMODYNAMIC CONTROL

Authors
BIRD P EAMES J FALLIS AG JONES RVH RODDIS M STURINO CF OSULLIVAN S WARREN S WESTWELL MS WORRALL J
Citation
P. Bird et al., REACTIONS OF EPISULFONIUM IONS FROM THE SULFENYLATION OF ALKENES AND FROM PHENYLTHIO MIGRATION - KINETIC VS THERMODYNAMIC CONTROL, Tetrahedron letters, 36(11), 1995, pp. 1909-1912
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
11
Year of publication
1995
Pages
1909 - 1912
Database
ISI
SICI code
0040-4039(1995)36:11<1909:ROEIFT>2.0.ZU;2-1
Abstract
The formation of the same cyclic ethers from the sulfenylation of unsa turated alcohols and from acid catalysed phenylthio migration on diols via the same intermediate can be explained by kinetic and thermodynam ic control. Both reactions are synthetically useful. A result from a p revious Tetrahedron Letter is corrected.