E. Nasr et al., ESTERIFICATION OF STEARIC-ACID USING LIGHT ALCOHOLS - HOMOGENEOUS CATALYSIS WITH TITANATES, Canadian journal of chemical engineering, 73(1), 1995, pp. 129-134
Stearic acid esterification with low boiling alcohols using alkyl tita
nate compounds is performed in a semi-continuous reactor. The kinetic
study of the reaction at high temperature (for which titanates are mor
e efficient) requires to include the uncatalyzed reaction. The signifi
cance of the catalyst is specified; the nature of the active species,
depending on rapid exchange reactions is also discussed.