AN ESR ANALYSIS OF C60S16

Citation
K. Tanaka et al., AN ESR ANALYSIS OF C60S16, Chemical physics letters, 235(3-4), 1995, pp. 217-220
Citations number
23
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
235
Issue
3-4
Year of publication
1995
Pages
217 - 220
Database
ISI
SICI code
0009-2614(1995)235:3-4<217:AEAOC>2.0.ZU;2-E
Abstract
The electron spin resonance (ESR) spectrum of C60S16 has been analyzed . It has been found that this compound has radical spins of only one s pin per 10(3)-10(4) C-60 molecules. In this sense, C60S16 is an essent ially neutral van der Waals complex. Nonetheless, the observed anisotr opy of the ESR lineshape suggests that rotation and pseudorotation of C-60(-) in C60S16 is suppressed even at room temperature.